Product ID:8031, WELDERS ANTI SPATTER
MSDS Date:07/28/1986
FSC:6850
NIIN:00N030914
MSDS Number: BPGVY

CROWN INDUSTRIAL PRODUCTS CO INC

12603 STATE LINE RD
HEBRON, IL 60034
US

Emergency Phone: 815-648-2424;815-338-2141

Info Phone: 815-648-2424

Preparer: ROBERT E. BAYTON

Cage: 92381

CROWN INDUSTRIAL PRODUCTS CO

350 HEBRON, IL 60034 US

Telephone: 815-648-2424

Cage: 92381

METHANE, DICHLORO-;(METHYLENE CHLORIDE)

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 31-50%

OSHA PEL 1000 PPM;1250 STEL

ACGIH TLV: 1000 PPM;1250 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CARBON DIOXIDE

CAS: 124-38-9

RTECS: FF6400000

Fraction By Weight: 1-10%

OSHA PEL 5000 PPM

ACGIH TLV: 5000PPM/30000STEL;93

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:SHORTNESS OF BREATH,
DIZZINESS, LIGHT HEADEDNESS. ANESTHETIC EFFECTS MAY OCCUR AT HIGH
CONCENTRATIONS. INGEST:MAY CAUSE CHEMICAL PNEUMONIA IF ASPIRATED
INTO LUNGS. EYE:POSSIBLE IRRITANT. S KIN:SHORT CONTACT:NO
IRRITATION. PROLONGED OR REPEATED CONTACT: MINOR TO MILD IRRIT.
SKIN ABSORPTION:(EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE:GROUP 2 (NTP), GROUP
2B (IARC).
Effects of Overexposure:HLTH HAZ:VERY LOW TOXICITY. CHLOROCARBON/
CHLOROFLUOROCARBON (CFC) MATERIALS HAVE PRODUCED SENSITIZATION OF
THE MYOCARDIUM TO EPINEPHRINE TO IN LAB ANIMALS & COULD HAVE
SIMILAR EFFECT IN HUMANS. ADREN OMIMETICS (E.G., EPINEPHRINE) MAY
BE CONTRA-INDICATED EXCEPT FOR LIFE SUSTAINING USES IN HUMANS
ACUTELY OR (SUDAT)
Medical Cond Aggravated by Exposure:MAY CAUSE MYOCARDIAL IRRITABILITY.
AVOID EPINEPHRINE OR SIMILAR DRUGS IF AT ALL POSSIBLE.

First Aid:CALL MD. EYE:FLUSH WITH WATER FOR AT LEAST 15 MINUTES OR
UNTIL IRRITATION SUBSIDES. SKIN:REMOVE ALL CONTAMINATED CLOTHING
AND WASH SKIN WITH SOAP & WATER. INHAL:MOVE FROM EXPOSURE
IMMEDIATELY. IF BREA THING IRREGULAR OR STOPPED BEGIN ARTIFICIAL
RESPIRATION AND GIVE OXYGEN. INGEST:DRINK LARGE AMOUNTS OF WATER.
DO NOT INDUCE VOMITING.

Flash Point Method:TCC
Flash Point:NONE
Lower Limits:14.8%
Upper Limits:22%
Extinguishing Media:WATER FOG, BUT NOT FLAMMABLE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
& FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:TREAT AS CYLINDERS OF COMPRESSED GAS.
THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE CHLORIDES, FLUORIDES AND
PHOSGENE .

Spill Release Procedures:VENTILATE AREA. REMOVE ALL SOURCES OF
IGNITION. CLEAN UP WITH INERT MATERIALS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT SPRAY AROUND OPEN FLAMES OR
SPARKS. EXPOSURE TO HEAT OR SUNLIGHT OR WHERE TEMPERATURES EXCEED
120F MAY CAUSE BURSTING.
Other Precautions:AVOID SKIN CONTACT. USE ONLY AS DIRECTED. INTENTIONAL
MISUSE BY DELIB CONC VAPS MAY BE HARMFUL/FATAL. NO SMKNG IN AREA OF
USE. DO NOT USE IN GEN VICIN OF ARC WELDING, OPEN FLAMES OR HOT
SURFS. HEAT &/ OR UV RADIA MAY CAUSE FORMATION (SUPDAT)

Respiratory Protection:RESPIRATORY PROGRAMS SHOULD BE IN ACCORDANCE
WITH 29 CFR 1910.134. NIOSH/MSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL EXHAUST IS ADEQUATE.
Protective Gloves:POLYETHYLENE OR NEOPRENE GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:PROTECTIVE CLOTHING AND EQUIPMENT:SEE 29 CFR
1910.132 & 133.
Work Hygienic Practices:WASH SKIN WITH SOAP & WATER.
Supplemental Safety and Health
HMIS(LEVIEN) HAS ASSIGNED HCC OF G1 BASED ON METHYLENE
CHLORIDE(POISON,6.1,III)/CARBON DIOXIDE(GAS,2.2)..VP:85-95 PSIG
(AEROSOL). EFTS OF OVEREXP: CHRONICALLY EXPOSED TO CHLOROCARBONS OR
CFC'S. CHRONI C:PROLONGED EXPOUSRE MAY RESULT IN KIDNEY AND LIVER
DAMAGE. OTHER PREC:OF CHLORIDES, FLUORIDES AND PHOSGENE .

HCC:G1
Vapor Pres:SUPP DATA
Vapor Density:>1
Spec Gravity:>1
Evaporation Rate & Reference:<1 (ETHER=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR COLORLESS/ETHEREAL ODOR
Percent Volatiles by Volume:>97

Stability Indicator/Materials to Avoid:YES
AMINES, SODIUM, POTASSIUM, ALUMINUM, BERYLIUM AND MAGNESIUM.
Stability Condition to Avoid:OPEN FLAMES, SPARKS, ELECTRICAL ARCS.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY YIELD HCL,
SMALL AMOUNTS OF PHOSGENE & CHLORINE. FLUORIDES .

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE,
AND FEDERAL REGULATIONS. AEROSOL CONTAINERS:DO NOT PUNCTURE OR
INCINERATE. EMPTY CONTAINERS MAY BE DISPOSED OF THROUGH NORMAL
CHANNELS. FULL/PARTIALLY F ILLED CONTAINERS ARE CONSIDERED
HAZARDOUS WASTE.

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